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This dataset consists of groundwater levels measured within wells distributed across Watershed 3 at Hubbard Brook Experimental Forest from 2007-2020. Water levels are expressed as a depth (cm) from the soil surface. This dataset is a part of a larger project aimed at explaining the spatial and temporal variation in stream water chemistry at the headwater catchment scale using a framework based on the combined study of hydrology and soil development – hydropedology. The project will demonstrate how hydrology strongly influences soil development and soil chemistry, and in turn, controls stream water quality in headwater catchments. Understanding the linkages between hydrology and soil development can provide valuable information for managing forests and stream water quality. Feedbacks between soils and hydrology that lead to predictable landscape patterns of soil chemistry have implications for understanding spatial gradients in site productivity and suitability for species with differing habitat requirements or chemical sensitivity. Tools are needed that identify and predict these gradients that can ultimately provide guidance for land management and silvicultural decision making. Better integration between soil science, hydrology, and biogeochemistry will provide the conceptual leap needed by the hydrologic community to be able to better predict and explain temporal and spatial variability of stream water quality and understand water sources contributing to streamflow. These data were gathered as part of the Hubbard Brook Ecosystem Study (HBES). The HBES is a collaborative effort at the Hubbard Brook Experimental Forest, which is operated and maintained by the USDA Forest Service, Northern Research Station. 

Mineral weathering is an important soil-forming process driven by the interplay of water, organisms, solution chemistry, and mineralogy. The influence of hillslope-scale patterns of water flux on mineral weathering in soils is still not well understood, particularly in humid postglacial soils, which commonly harbor abundant weath- erable primary minerals. Previous work in these settings showed the importance of lateral hydrologic patterns to hillslope-scale pedogenesis. In this study, we hypothesized that there is a corresponding relationship between hydrologically driven pedogenesis and chemical weathering in podzols in the White Mountains of New Hamp- shire, USA. We tested this hypothesis by quantifying the depletion of plagioclase in the fine fraction (≤2 mm) of closely spaced, similar-age podzols along a gradient in topography and depth to bedrock that controls lateral water flow. Along this gradient, laterally developed podzols formed through frequent, episodic flushing by up- slope groundwater, and vertically developed podzols formed through characteristic vertical infiltration. We estimated the depletion of plagioclase-bound elements within the upper mineral horizons of podzols using mass transfer coefficients (τ) and quantified plagioclase losses directly through electron microscopy and microprobe analysis. Elemental depletion was significantly more pronounced in the upslope lateral eluvial (E horizon- dominant) podzols relative to lateral illuvial (B horizon-dominant) and vertical (containing both E and B hori- zons) podzols downslope, with median Na losses of ~74 %, ~56 %, and ~40 %, respectively. When comparing genetic E horizons, Na and Al were significantly more depleted in laterally developed podzols relative to vertically developed podzols. Microprobe analysis revealed that ~74 % of the plagioclase was weathered from the mineral pool of lateral eluvial podzols, compared to ~39 % and ~23 % for lateral illuvial podzols and vertically developed podzols, respectively. Despite this intense weathering, plagioclase remains the second most abundant mineral in soil thin sections. These findings confirm that the concept of soil development as occurring vertically does not accurately characterize soils in topographically complex regions. Our work improves the current understanding of pedogenesis by identifying distinct, short-scale gradients in mineral weathering shaped by local patterns of hydrology and topography. 

Chemical analyses were performed on sieved and dried soil samples collected for the Lateral Weathering project within Watershed 3, Hubbard Brook Experimental Forest, Woodstock, NH, USA from 2018-2020. Chemical information corresponds to horizons described in dataset HBR361, which were collected from pits described in the same dataset. Analyses include pH, C, N, exchangeable ions, secondary metals from citrate dithionite and ammonium oxalate in the dark, and total elemental content. These data were gathered as part of the Hubbard Brook Ecosystem Study (HBES). The HBES is a collaborative effort at the Hubbard Brook Experimental Forest, which is operated and maintained by the USDA Forest Service, Northern Research Station. 

Hbr363: WS3 One year of resin-extracted solutes from variably saturated soils The Lateral Weathering Study looks at spatial patterns of mineral weathering processes at Hubbard Brook Experimental Forest. This project is characterizing mineral and elemental depletion/enrichment, soil morphology and chemistry, solute transport, and groundwater chemistry along hydropedological gradients. This dataset provides the total elemental mass of inorganic solutes (Ca, Na, Mg, Al, Fe, Mn, P, and S) as well as dissolved organic carbon (DOC) that were extracted off resins installed into shallow groundwater wells (~30-100cm) in Watershed 3. Resin packs were deployed for a total of one year (August 2019-2020) with four consecutive deployment periods, to avoid overloading resin ion capacity. Total mass for each solute was accounted for an entire resin pack, which was 5cm in height and 5cm in diameter, containing approximately 90 g of resin. Resin packs were installed in three different topographic positions along three transects (sites = 9), to characterize solute mass fluxes through different hydropedological units. 

This dataset consists of chemical analyses of subsurface water samples collected from Watershed 3, Hubbard Brook Experimental Forest, Woodstock, NH, USA from 2009-2020. Samples include groundwater samples pumped from monitoring wells, grab samples of natural groundwater seeps, and soil water samples pumped from Prenart lysimeters. For samples from wells where water table was monitored, depth to water table is given. These data were gathered as part of the Hubbard Brook Ecosystem Study (HBES). The HBES is a collaborative effort at the Hubbard Brook Experimental Forest, which is operated and maintained by the USDA Forest Service, Northern Research Station. 

Soil pits and horizons were described and sampled as part of the Lateral Weathering project within Watershed 3, Hubbard Brook Experimental Forest, Woodstock, NH, USA from 2018-2020. Soil pits were dug and described using NRCS methods. When possible, physical samples were archived in the Hubbard Brook Sample Archive. These data were gathered as part of the Hubbard Brook Ecosystem Study (HBES). The HBES is a collaborative effort at the Hubbard Brook Experimental Forest, which is operated and maintained by the USDA Forest Service, Northern Research Station. 

Soil pits and horizons were described and sampled as part of the Lateral Weathering project within Watershed 3, Hubbard Brook Experimental Forest, Woodstock, NH, USA from 2018-2020. Soil pits were dug and described using NRCS methods. When possible, physical samples were archived in the Hubbard Brook Sample Archive. These data were gathered as part of the Hubbard Brook Ecosystem Study (HBES). The HBES is a collaborative effort at the Hubbard Brook Experimental Forest, which is operated and maintained by the USDA Forest Service, Northern Research Station.